Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.11851/6754
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dc.contributor.authorDuran, Hatice-
dc.contributor.authorSteinhart, Martin-
dc.contributor.authorButt, Hans Juergen-
dc.contributor.authorFloudas, George-
dc.date.accessioned2021-09-11T15:43:26Z-
dc.date.available2021-09-11T15:43:26Z-
dc.date.issued2011en_US
dc.identifier.issn1530-6984-
dc.identifier.issn1530-6992-
dc.identifier.urihttps://doi.org/10.1021/nl200153c-
dc.identifier.urihttps://hdl.handle.net/20.500.11851/6754-
dc.description.abstractThe crystallization of highly isotactic polypropylene confined in self-ordered nanoporous alumina is studied by differential scanning calorimetry. A transformation from a predominantly heterogeneous to predominantly homogeneous nucleation takes place if the pore diameter is smaller than 65 nm. Crystallization is suppressed with decreasing pore size, and the absence of nucleation below 20 nm pores indicates the critical nucleus size. The results reported here might enhance the understanding of nanocomposites containing semicrystalline polymers and reveal design criteria for polymeric nanofibers with tailored mechanical and optical pioperties.en_US
dc.description.sponsorshipJohn S. Latsis public benefit Foundation; German Research FoundationGerman Research Foundation (DFG) [SPP 1369]en_US
dc.description.sponsorshipTechnical support by Dr. M. Mondeshki (NMR), K. Sklarek (self-ordered AAO membranes), G. Glasser (SEM), and J. Thiel (DSC) are gratefully acknowledged. G.F. acknowledges financial support by the John S. Latsis public benefit Foundation. H.D. and M.S. gratefully acknowledge financial support from the German Research Foundation (SPP 1369).en_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofNano Lettersen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectNucleationen_US
dc.subjectconstrained crystallizationen_US
dc.subjectnanoporous aluminaen_US
dc.subjectisotactic polypropyleneen_US
dc.subjectcalorimetryen_US
dc.titleFrom Heterogeneous To Homogeneous Nucleation of Isotactic Poly(propylene) Confined To Nanoporous Aluminaen_US
dc.typeArticleen_US
dc.departmentFaculties, Faculty of Engineering, Department of Material Science and Nanotechnology Engineeringen_US
dc.departmentFakülteler, Mühendislik Fakültesi, Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümütr_TR
dc.identifier.volume11en_US
dc.identifier.issue4en_US
dc.identifier.startpage1671en_US
dc.identifier.endpage1675en_US
dc.authorid0000-0001-6203-3906-
dc.authorid0000-0001-5391-2618-
dc.authorid0000-0002-5241-8498-
dc.authorid0000-0001-6203-3906-
dc.identifier.wosWOS:000289341500048en_US
dc.identifier.scopus2-s2.0-79954520055en_US
dc.institutionauthorDuran Durmuş, Hatice-
dc.identifier.pmid21355534en_US
dc.identifier.doi10.1021/nl200153c-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopusqualityQ1-
item.openairetypeArticle-
item.languageiso639-1en-
item.grantfulltextnone-
item.fulltextNo Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
crisitem.author.dept02.6. Department of Material Science and Nanotechnology Engineering-
Appears in Collections:Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümü / Department of Material Science & Nanotechnology Engineering
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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