Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.11851/8836
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dc.contributor.authorArshad F.-
dc.contributor.authorTahir A.-
dc.contributor.authorHaq T.U.-
dc.contributor.authorDuran H.-
dc.contributor.authorHussain I.-
dc.contributor.authorSher F.-
dc.date.accessioned2022-11-30T19:20:56Z-
dc.date.available2022-11-30T19:20:56Z-
dc.date.issued2022-
dc.identifier.issn0360-3199-
dc.identifier.urihttps://doi.org/10.1016/j.ijhydene.2022.08.187-
dc.identifier.urihttps://hdl.handle.net/20.500.11851/8836-
dc.description.abstractElectrocatalytic water electrolysis is the most promising clean and efficient process for pure and clean generation of hydrogen. However, water oxidation reaction requires a large overpotential owing to its slow kinetics, causing a lower efficiency of hydrogen production and high energy consumption. Herein, we report the bimetallic NiCu interconnected porous nanostructures on copper foil (NiCu@Cu) prepared by hydrogen bubbles templating electrodeposition technique for methanol oxidation reaction (MOR), which replaces the kinetically sluggish water oxidation reaction and enhances the hydrogen production with lower energy input. With their high macroporosity, interconnected growth on copper foil with excellent conductivity and easy flow of electrolyte on electrode interface, and stabilization of active sites due to bimetallic synergistic effects, the NiCu@Cu electrocatalysts exhibit outstanding activities for HER and MOR. The NiCu@Cu requiring just 1.32 V anodic potential vs RHE at 10 mA cm?2 for MOR which is significantly lower than that for water oxidation reaction. Moreover, the electrolyzer using NiCu@Cu/NiCu@Cu for anodic MOR and cathodic H2 production only needs a low input voltage of 1.45 V to deliver a current density of 10 mA cm?2 with impressive durability. © 2022 Hydrogen Energy Publications LLCen_US
dc.description.sponsorshipLahore University of Management Sciences, LUMSen_US
dc.description.sponsorshipThe authors FA and FS appreciate the financial support provided by the Lahore University of Management Sciences , Pakistan.en_US
dc.language.isoenen_US
dc.publisherElsevier Ltden_US
dc.relation.ispartofInternational Journal of Hydrogen Energyen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBubble templating electrodepositionen_US
dc.subjectEnergy-saving hydrogen productionen_US
dc.subjectMethanol-assisted hydrogen productionen_US
dc.subjectNiCu porous Interconnected networken_US
dc.subjectSelective methanol oxidation reactionen_US
dc.subjectAnodic oxidationen_US
dc.subjectBinary alloysen_US
dc.subjectCopperen_US
dc.subjectElectrocatalystsen_US
dc.subjectElectrodepositionen_US
dc.subjectElectrodesen_US
dc.subjectElectrolytesen_US
dc.subjectEnergy conservationen_US
dc.subjectEnergy utilizationen_US
dc.subjectMethanolen_US
dc.subjectNanostructuresen_US
dc.subjectReaction kineticsen_US
dc.subjectBubble templating electrodepositionen_US
dc.subjectEnergy savingsen_US
dc.subjectEnergy-saving hydrogen productionen_US
dc.subjectEnergy-savingsen_US
dc.subjectInterconnected networken_US
dc.subjectMethanol oxidation reactionsen_US
dc.subjectMethanol-assisted hydrogen productionen_US
dc.subjectNicu porous interconnected networken_US
dc.subjectSelective methanol oxidation reactionen_US
dc.subjectTemplatingen_US
dc.subjectHydrogen productionen_US
dc.titleFabrication of Nicu Interconnected Porous Nanostructures for Highly Selective Methanol Oxidation Coupled With Hydrogen Evolution Reactionen_US
dc.typeArticleen_US
dc.identifier.wosWOS:000893422500014en_US
dc.identifier.scopus2-s2.0-85138551404en_US
dc.institutionauthorDuran Durmus, Hatice-
dc.identifier.doi10.1016/j.ijhydene.2022.08.187-
dc.authorscopusid57200142187-
dc.authorscopusid57900916100-
dc.authorscopusid57721535100-
dc.authorscopusid25633500900-
dc.authorscopusid7103384870-
dc.authorscopusid8070394600-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopusqualityQ1-
dc.ozel2022v3_Editen_US
item.openairetypeArticle-
item.languageiso639-1en-
item.grantfulltextnone-
item.fulltextNo Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
crisitem.author.dept02.6. Department of Material Science and Nanotechnology Engineering-
Appears in Collections:Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümü / Department of Material Science & Nanotechnology Engineering
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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