Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.11851/6506
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dc.contributor.authorFarrukh, Aleeza-
dc.contributor.authorAkram, Attia-
dc.contributor.authorGhaffar, Abdul-
dc.contributor.authorHanif, Sara-
dc.contributor.authorHamid, Almas-
dc.contributor.authorDuran, Hatice-
dc.contributor.authorYameen, Basit-
dc.date.accessioned2021-09-11T15:37:00Z-
dc.date.available2021-09-11T15:37:00Z-
dc.date.issued2013en_US
dc.identifier.issn1944-8244-
dc.identifier.issn1944-8252-
dc.identifier.urihttps://doi.org/10.1021/am400427n-
dc.identifier.urihttps://hdl.handle.net/20.500.11851/6506-
dc.description.abstractHighly efficient removal of mercury(II) ions (Hg-II) from water has been reported by employing polymer-brush-functionalized magnetic nanoparticles (MNPs). Surface-initiated conventional radical polymerization (SI-cRP) was used to grow poly(2-aminoethyl methacrylate hydrochloride) (poly-AEMA center dot HCl) polymer chains on magnetite nanoparticles (Fe3O4), followed by the transformation of pendant amino groups into dithiocarbamate (DTC) groups, which showed high chelating affinity toward Hg-II ions. This polymer-brush-based DTC-functionalized MNP (MNPs-polyAEMA center dot DTC) platform showed the complete removal of Hg-II from aqueous solutions. The Hg-II ion removal capacity and efficiency of MNPs-polyAEMA center dot DTC were compared with its monolayer analogue, which was derived from the direct transformation of amino groups of (3-aminopropyl) triethoxysilane (APTES)-functionalized MNPs (MNPs-APTES) to DTC functional groups (MNPs-DTC). The surface chemical modifications and higher chelating functional group density, in the case of MNPs-polyAEMA center dot DTC, were ascertained by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), physical property measurement system (PPMS), attenuated total reflectance infrared (ATR-IR) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The Hg-II ion removal capacity and efficiency of monolayer and polymer-brush-based DTC-functionalized MNPs (MNPs-DTC and MNPs-polyAEMA center dot DTC, respectively) were evaluated and compared by studying the effect of various factors on the percentage removal of Hg-II such as adsorbent amount, temperature, and contact time. Furthermore, the adsorption behavior of MNPs-DTC and MNPs-polyAEMA center dot DTC was analyzed by applying Langmuir and Freundlich adsorption isotherm models. In addition, the adsorption thermodynamics, as well as the adsorption kinetics, were also evaluated in detail. The higher surface functional group density of MNPs-polyAEMA center dot DTC led to superior remediation characteristics toward Hg-II ions than its monolayer analogue.en_US
dc.description.sponsorshipHEC; LUMSen_US
dc.description.sponsorshipB.Y. acknowledges financial support from HEC and a start-up grant from LUMS. H.D. and B.Y. thank UNAM, Bilkent University for technical support for XPS, PPMS, TEM, and TGA analysis.en_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofAcs Applied Materials & Interfacesen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectmagnetic nanoparticlesen_US
dc.subjectpolymer brushesen_US
dc.subjectdithiocarbamateen_US
dc.subjectmercuryen_US
dc.subjectadsorbenten_US
dc.titleDesign of Polymer-Brush-Grafted Magnetic Nanoparticles for Highly Efficient Water Remediationen_US
dc.typeArticleen_US
dc.departmentFaculties, Faculty of Engineering, Department of Material Science and Nanotechnology Engineeringen_US
dc.departmentFakülteler, Mühendislik Fakültesi, Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümütr_TR
dc.identifier.volume5en_US
dc.identifier.issue9en_US
dc.identifier.startpage3784en_US
dc.identifier.endpage3793en_US
dc.authorid0000-0001-6203-3906-
dc.authorid0000-0001-6203-3906-
dc.authorid0000-0002-3794-246X-
dc.authorid0000-0002-0711-0419-
dc.identifier.wosWOS:000318839100042en_US
dc.identifier.scopus2-s2.0-84877341178en_US
dc.institutionauthorDuran Durmuş, Hatice-
dc.identifier.pmid23570443en_US
dc.identifier.doi10.1021/am400427n-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopusqualityQ1-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextnone-
item.fulltextNo Fulltext-
item.openairetypeArticle-
item.cerifentitytypePublications-
item.languageiso639-1en-
crisitem.author.dept02.6. Department of Material Science and Nanotechnology Engineering-
Appears in Collections:Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümü / Department of Material Science & Nanotechnology Engineering
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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