Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.11851/7565
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dc.contributor.authorDuran, Hatice-
dc.contributor.authorYameen, Basit-
dc.contributor.authorKhan, Hadayat Ullah-
dc.contributor.authorFoerch, Renate-
dc.contributor.authorKnoll, Wolfgang-
dc.date.accessioned2021-09-11T15:57:53Z-
dc.date.available2021-09-11T15:57:53Z-
dc.date.issued2013en_US
dc.identifier.issn1381-5148-
dc.identifier.issn1873-166X-
dc.identifier.urihttps://doi.org/10.1016/j.reactfunctpolym.2013.01.007-
dc.identifier.urihttps://hdl.handle.net/20.500.11851/7565-
dc.description.abstractThe potential of pulsed plasma deposited polyallylamine (PAA) adlayer has been successfully demonstrated for fabrication of polypeptide brushes functionalized soft flexible polymeric surfaces. Polymeric substrates functionalized with the plasma deposition PAA adlayer resulted in polymeric surfaces functionalized with amino groups, which are the suitable initiating moieties for ring-opening polymerization (ROP) of N-carboxy anhydride of benzyl-L-glutamate (NCA-BLG) monomer. Poly(gamma-benzyl-L-glutamate) (PBLG) brushes were grown on PM functionalized polypropylene (PP), and polytetrafluoroethylene (PTFE) polymeric substrates. These substrates were intentionally chosen for their inert chemical nature towards most wet chemical surface modification reactions. Surface grafted thin films of poly(gamma-benzyl-L-glutamate) PBLG on both the PP and PTFE polymeric substrates yielded high density PBLG brushes. PBLG chain orientation, secondary structure and grafting density were characterized by infra-red spectroscopy. The synthesis of PBLG brushes on a flexible polymeric substrate is unprecedented and technologically important, since PBLG possess good electro-optical activity. Analysis of brush layers by Attenuated Total Reflectance Infra-Red (ATR-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS) as well as atomic force microscopy (AFM) fully corroborated the success of the plasma activated soft surface grafting approach. (C) 2013 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipEuropean UnionEuropean Commission; Mari Curie Intra-European Fellowship [MEIF-CT-2005-024731]; Higher Education Commission (HEC) of PakistanHigher Education Commission of Pakistan; Deutscher Aka-demischer Austauschdienst (DAAD)Deutscher Akademischer Austausch Dienst (DAAD) [A/04/30795]en_US
dc.description.sponsorshipH.D. thanks the European Union, Mari Curie Intra-European Fellowship (MEIF-CT-2005-024731) for financial support. We also thank Daniela Moessner (IMTEK-University of Freiburg, Germany) for XPS analysis and Y. Ming (MPI-P, Mainz Germany) for AFM measurements. B.Y. acknowledges financial support from the Higher Education Commission (HEC) of Pakistan and Deutscher Aka-demischer Austauschdienst (DAAD) (Code #A/04/30795).en_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofReactive & Functional Polymersen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPolymer brushesen_US
dc.subjectPlasma polymerizationen_US
dc.subjectPolypeptideen_US
dc.subjectSurface graftingen_US
dc.subjectSoft polymeric surfacesen_US
dc.titleSurface-initiated ring opening polymerization of N-carboxy anhydride of benzyl-L-glutamate monomers on soft flexible substratesen_US
dc.typeArticleen_US
dc.departmentFaculties, Faculty of Engineering, Department of Material Science and Nanotechnology Engineeringen_US
dc.departmentFakülteler, Mühendislik Fakültesi, Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümütr_TR
dc.identifier.volume73en_US
dc.identifier.issue3en_US
dc.identifier.startpage606en_US
dc.identifier.endpage612en_US
dc.authorid0000-0001-6203-3906-
dc.authorid0000-0001-6203-3906-
dc.identifier.wosWOS:000316512000022en_US
dc.identifier.scopus2-s2.0-84873276976en_US
dc.institutionauthorDuran Durmuş, Hatice-
dc.identifier.doi10.1016/j.reactfunctpolym.2013.01.007-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopusqualityQ1-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextnone-
item.fulltextNo Fulltext-
item.openairetypeArticle-
item.cerifentitytypePublications-
item.languageiso639-1en-
crisitem.author.dept02.6. Department of Material Science and Nanotechnology Engineering-
Appears in Collections:Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümü / Department of Material Science & Nanotechnology Engineering
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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