Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.11851/10699
Title: Continuous conducting architecture developed by supporting Prussian blue analogue on metal-organic framework derived carbon-doped manganese-oxide nanorods for high-performance sodium-ion batteries
Authors: Ullah, Irfan
Saeed, Roheen
Inayat, Abid
Zubair, Muhammad
Wu, Xianyong
Duran, Hatice
Haider, Ali
Keywords: Redox active support
Manganese-oxide
Incorporation
Prussian blue
Sodium ion
Batteries
Superior Cathode
Composites
Storage
Design
Issue Date: 2023
Publisher: Elsevier Science Sa
Abstract: Prussian blue analogues (PBA) are regarded as promising cathode materials for sodium-ion batteries (SIBs) owing to their open framework with large interstitial sites to accommodate Na+ ions. However, PBA suffer from low electronic conductivity and mechanical instability, which may be improved by their structural modification leading to enhanced kinetics. In this regard, we report an in-situ integration of ultra-small PBA cubes into threedimensional metal organic framework (MOF) derived carbon-doped manganese oxide nanorods (C-Mn2O3), which form a continuous conductive architecture with intimate PBA/C-Mn2O3 contact. The C-Mn2O3 nanorods provide nucleation sites for the growth of PBA cubes and further act as the electronic pathway to improve electrode reaction kinetics. This hierarchical configuration effectively buffers the lattice expansion, which improve the structural stability of NiCoPBA. Consequently, the composite exhibits promising performance in aqueous Na+ batteries. Specifically, it delivers a high capacity of 97 mAh/g within a narrow potential window of and retained 82% capacity for 1000 cycles in aqueous electrolyte. It shows even higher capacity of 136 mAh/g and similar capacity retention (76% after 1000 cycles) in non-aqueous electrolytes. The promising performance of developed materials demonstrates the significant impact decreasing the size of PBA cubes has on the capacity by reducing the diffusion pathways and thus facilitating intercalation/deintercalation within the cubes. This study offers new insights of exploiting redox-active substrates to modify and stabilize PBA materials for energy storage applications.
URI: https://doi.org/10.1016/j.jallcom.2023.171223
https://hdl.handle.net/20.500.11851/10699
ISSN: 0925-8388
1873-4669
Appears in Collections:Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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