Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.11851/6493
Title: Design and Fabrication of Branched Polyamine Functionalized Mesoporous Silica: An Efficient Absorbent for Water Remediation
Authors: Nayab, Sana
Farrukh, Aleeza
Oluz, Zehra
Tuncel, Eylül
Tariq, Saadia Rashid
Rahman, Habib ur
Yameen, Basit
Keywords: mesoporous silica
branched polyamine
surface modification
adsorbent
water remediation
Issue Date: 2014
Publisher: Amer Chemical Soc
Abstract: A novel branched polyamine (polyethyleneimine, PEI) functionalized mesoporous silica (MS) adsorbent is developed via a facile "grafting-to" approach. X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy verified the effective surface functionalization of MS with monolayer and polymer. The transmission electron microscopy (TEM) was employed to reveal the morphology of the fabricated materials. The adsorption behavior of the polyamine functionalized mesoporous silica (MS-PEI) is assessed against anionic dyes. The adsorbent characteristics of MS-PEI are compared with a monolayer platform comprising of 3-aminopropyltriethoxy silane (APTES) functionalized mesoporous silica (MS-APTES). The adsorption behavior of the MS-PEI and MS-APTES toward anionic dyes is further evaluated by studying the effect of adsorbent dosage, pH, contact time, and temperature. Langmuir and Freundlich isotherm models are employed to understand the adsorption mechanism. The obtained kinetic data support a pseudo-second-order adsorption behavior for both monolayer and polymer functionalized MS. The associated thermodynamic parameters (Delta G degrees, Delta H degrees, and Delta S degrees) reveal that the process of adsorption with MS-PEI is more spontaneous and energetically favored as compared to the adsorption with MS-APTES. Taken together, the novel adsorbent system derived from a combination of MS and branched polymer (MS-PEI) shows the higher absorption efficiency and capacity toward the anionic dyes than the monolayer based adsorbent (MS-APTES).
URI: https://doi.org/10.1021/am500123k
https://hdl.handle.net/20.500.11851/6493
ISSN: 1944-8244
Appears in Collections:Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümü / Department of Material Science & Nanotechnology Engineering
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Show full item record

CORE Recommender

SCOPUSTM   
Citations

90
checked on Sep 23, 2022

WEB OF SCIENCETM
Citations

95
checked on Sep 24, 2022

Page view(s)

20
checked on Feb 6, 2023

Google ScholarTM

Check

Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.